Response to Comment on “Novel Perfluoroalkyl Ether Carboxylic Acids (PFECAs) and Sulfonic Acids (PFESAs)”: Overlooked Interactions with Perfluorooctanoic Acid
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چکیده
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Reaction of Stannyl Esters of Phosphorus Acids with Sulfonic Acids Chlorides and Carboxylic Acids Anhydrides. A Novel Synthesis of Phosphoric-Sulfonic and Phosphoric-Carboxylic Anhydrides
Mixed anhydrides of phosphorus sulfonic acids RR'P(O)OSOzR" 1 are of interest in the biological transfer of sulfates'. In the chemical synthesis of oligonucleotides, phosphoric sulfonic anhydrides 1 (R', R = nucleoside) are postulated as important and reactive intermediatesw-s-. Anhydrides 1 were also suggested as intermediates in biooxidation of thiolophosphates'. Structural analogues of anhyd...
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Since 2000 there has been an on-going industrial transition to replace long-chain perfluoroalkyl carboxylic acids(PFCAs), perfluoroalkane sulfonic acids (PFSAs) and their precursors. To date, information on these replacements including their chemical identities, however, has not been published or made easily accessible to the public, hampering risk assessment and management of these chemicals. ...
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متن کاملToxicokinetics of perfluoroalkyl carboxylic acids with different carbon chain lengths in mice and humans.
OBJECTIVES Perfluoroalkyl carboxylic acids (PFCAs) consist of analogs with various carbon chain lengths. Their toxicokinetics have remained unexplored except in the case of perfluorooctanoic acid (8 carbon chemicals). This study aimed to investigate the toxicokinetics of PFCAs with six to fourteen carbon atoms (C6 to C14) in mice and humans. METHODS We applied a two-compartment model to mice ...
متن کاملINTERACTIONS OF AMMONIUM SMECTITE WITH LOW MOLECULAR WEIGHT CARBOXYLIC ACIDS Shortened title NH4-CLAY-CARBOXYLIC ACIDS INTERACTION
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ژورنال
عنوان ژورنال: Environmental Science & Technology
سال: 2021
ISSN: 0013-936X,1520-5851
DOI: 10.1021/acs.est.1c02603